Lithium elemental and isotopic disequilibrium in minerals from peridotite xenoliths from Shangzhi, NE China: products of recent melt/fluid-peridotite interaction

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单位State Key Laboratory of Ore Deposit Geochemistry,Instituteof Geochemistry,Chinese Academy of Sciences,Guiyang 550081,PR China;University of Chinese Academy of Sciences,Beijing 100049,PR China
来源中国地球化学学报(英文版)
出版年2018
期号第5期
摘要
Lithium elemental and isotopic disequilibrium has frequently been observed in the continental and oceanic mantle xenoliths, but its origin remains controversial. Here, we present a combined elemental and Li isotopic study on variably metasomatised peridotite xenoliths entrained in the Cenozoic basalts from Shangzhi in Northeast (NE) China that provides insight into this issue. Li concentration (0.3-2.7 ppm) and δ^7Li (mostly 2‰-6‰) in olivine from the Shangzhi peridotites are similar to the normal mantle values and show roughly negative correlations with the indices of melt extraction (such as modal olivine and whole rock MgO). These features are consistent with variable degrees of partial melting. In contrast, clinopyroxene from the Shangzhi xenoliths shows significant Li enrichment (0.9-6.1 ppm) and anomalously light δ^7Li (- 13.8‰ to 7.7‰) relative to normal mantle values. Such features can be explained by Li diffusion from silicate melts or Li-rich fluids occurring over a very short time (several minutes to several hours). Moreover, the light Li isotopic composi- tions preserved in some bulk samples also indicate that these percolated melts/fluids have not had enough time to isotopically equilibrate with the bulk peridotite. We thus emphasize that Li isotopic fractionation in the Shangzhi mantle xenoliths is mainly related to Li diffusion from silicate melts or Li-rich fluids that took place shortly before or coincident with their entrainment into the host magmas.

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