Urbanization poses significant challenges for fault investigation, as it can obscure or even hide surface fault expressions and limit access to potential study sites. This paper reports the preliminary results of Electrical Resistivity Tomography combined with geological field surveys in the urbanized area of Villa d’Agri (Marsicovetere, Basilicata Region, Southern Italy), which has undergone significant expansion in recent decades. This area is located at the northeastern border of the High Agri Valley, characterized by the Eastern Agri Fault System, one of the fault systems believed to have caused the M 7.0 earthquake in 1857 in Southern Italy. The combined use of Electrical Resistivity Tomography and geological field investigations in previously inadequately explored areas, along with the reprocessing of data provided by the technical office of Marsicovetere, allowed imaging of a previously unknown fault and reconstruction of sedimentary cover and substratum geometries, particularly in the urban and peri-urban sectors of Villa d’Agri. These preliminary findings provide valuable insights for geological and structural studies and have prompted the attention of the municipal decision makers, supporting further research aimed at enhancing urban management and seismic risk assessment.